Expeditious Synthesis of the Cores of Naturally Occurring Cyclic Polyethers using a Divergent Ring Rearrangement Metathesis Strategy

被引：8

作者：

Escavabaja, Philippe ^{[1
]}

Viala, Jacques ^{[1
]}

Coquerel, Yoann ^{[1
]}

Rodriguez, Jean ^{[1
]}

机构：

[1] Aix Marseille Univ, CNRS, Inst Sci Mol Marseille, UMR 7313,Serv 531, F-13397 Marseille 20, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 17期

关键词：

homogeneous catalysis; metathesis; natural products; rearrangement; synthetic methods; DOMINO METATHESIS; STEREOSELECTIVE-SYNTHESIS; HYBRID MOLECULES; MARDI CASCADE; AMINO-ACID; DYSIHERBAINE; ACETOGENINS; ANALOGS; CANCER;

D O I：

10.1002/adsc.201200665

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Ring rearrangement metathesis (RRM) strategies are proposed for the expeditious synthesis of the cores of naturally occurring cyclic polyethers of the dysiherbaine and acetogenin families, as well as a hybrid compound, from 8-oxabicyclo[3.2.1]octenes.

引用

页码：3200 / 3204

页数：5

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