Expeditious Synthesis of the Cores of Naturally Occurring Cyclic Polyethers using a Divergent Ring Rearrangement Metathesis Strategy

被引：8

作者：

Escavabaja, Philippe ^{[1
]}

Viala, Jacques ^{[1
]}

Coquerel, Yoann ^{[1
]}

Rodriguez, Jean ^{[1
]}

机构：

[1] Aix Marseille Univ, CNRS, Inst Sci Mol Marseille, UMR 7313,Serv 531, F-13397 Marseille 20, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 17期

关键词：

homogeneous catalysis; metathesis; natural products; rearrangement; synthetic methods; DOMINO METATHESIS; STEREOSELECTIVE-SYNTHESIS; HYBRID MOLECULES; MARDI CASCADE; AMINO-ACID; DYSIHERBAINE; ACETOGENINS; ANALOGS; CANCER;

D O I：

10.1002/adsc.201200665

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Ring rearrangement metathesis (RRM) strategies are proposed for the expeditious synthesis of the cores of naturally occurring cyclic polyethers of the dysiherbaine and acetogenin families, as well as a hybrid compound, from 8-oxabicyclo[3.2.1]octenes.

引用

页码：3200 / 3204

页数：5

共 11 条

[1] Stereoselective synthesis of the naturally occurring lactones (-)-osmundalactone and (-)-muricatacine using ring-closing metathesis
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EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2002, 2002 (15) : 2649 - 2655
[2] Synthesis of spiroketals under neutral conditions via a type III ring-rearrangement metathesis strategy
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[3] Regioselective formation of interlocked dicarba bridges in naturally occurring cyclic peptide toxins using olefin metathesis
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van Lierop, Bianca J.
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[4] Total Synthesis of Amphidinolide T3 Using Ring-Closing Metathesis and Asymmetric Dihydroxylation Strategy
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[5] A total synthesis of (±)-1-desoxyhypnophilin:: using ring closing metathesis for the construction of cyclic enones
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[6] Design and synthesis of novel propellanes by using Claisen rearrangement and ring-closing metathesis as the key steps
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[8] Stereoselective Synthesis of Functionalized Cyclic Amino Acid Derivatives via a [2,3]-Stevens Rearrangement and Ring-Closing Metathesis
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[9] Synthesis of model BC bicycles of taxol using C10-C11 ring-closing metathesis strategy
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[10] Novel methodology for the synthesis of the benz[a]anthracene skeleton of the angucyclines using a Suzuki-Miyaura/isomerization/ring closing metathesis strategy
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