Functionalization of [60]fullerene using a novel chemical vapor modification method

被引：5
|
作者：
Vieira, SMC
Ahmed, W
Birkett, PR
Rego, CA
Kotsiris, S
Drewello, T
机构：
[1] Manchester Metropolitan Univ, Dept Chem & Mat, Manchester M1 5GD, Lancs, England
[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
来源：
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2004年 / 12卷 / 1-2期
关键词：
chemical vapor modification; 60]fullerene; nanotube; H-1; NMR;
D O I：
10.1081/FST-120027147
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Gas phase reactions of [60]fullerene with hydrogen atoms and/or methyl radicals have been performed by hot filament chemical vapor modification (CVM) to produce hydrogenated and/or methylated [60]fullerene. The CVM process parameters such as the time of reaction, pressure, and percentage of methane diluted in hydrogen have been varied so as to obtain the addended fullerene reaction products. Mass spectrometry and H-1 NMR techniques were used to characterize the reaction products obtained.
引用
收藏
页码：139 / 145
页数：7
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