Optical Properties of Aqueous Solutions of Dimethyl Sulfoxide and Application of Refractometry for Monitoring Their Composition

被引:7
|
作者
Akmarov, K. A. [1 ]
Lapshov, S. N. [1 ]
Sherstobitova, A. S. [1 ]
Yas'kov, A. D. [1 ]
机构
[1] St Petersburg Natl Res Univ Informat Technol Mech, St Petersburg 197101, Russia
关键词
dimethyl sulfoxide; optical properties; refractive index; ultraviolet absorption;
D O I
10.1007/s10812-013-9814-4
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
In line with the demands of industrial refractometric technologies, we have measured the concentration and temperature dependences of the refractive index n(k; t) of aqueous solutions of dimethyl sulfoxide (DMSO), and also its temperature coefficient dn(k; t)/dt. The transmission spectra of these solutions with different concentrations k = 20-90% at lambda = 200-760 nm are compared with the refractive index in the visible wavelength region. We give a brief description of an optoelectronic refractometric sensor for monitoring the composition of DMSO solutions in the production line and software-based methods for adjustment and calibration of the sensor.
引用
收藏
页码:610 / 614
页数:5
相关论文
共 50 条
  • [1] Optical Properties of Aqueous Solutions of Dimethyl Sulfoxide and Application of Refractometry for Monitoring Their Composition
    K. A. Akmarov
    S. N. Lapshov
    A. S. Sherstobitova
    A. D. Yasʼkov
    Journal of Applied Spectroscopy, 2013, 80 : 610 - 614
  • [2] Transport properties of dimethyl sulfoxide aqueous solutions
    Nieto-Draghi, C
    Avalos, JB
    Rousseau, B
    JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (09): : 4782 - 4789
  • [3] Thermotropic properties of dioleoylphosphatidylethanolamine in aqueous dimethyl sulfoxide solutions
    Yu, ZW
    Williams, WP
    Quinn, PJ
    ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 1996, 332 (01) : 187 - 195
  • [4] Preferential solvation and ion association properties in aqueous dimethyl sulfoxide solutions
    Krishnamoorthy, Anand Narayanan
    Zeman, Johannes
    Holm, Christian
    Smiatek, Jens
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (45) : 31312 - 31322
  • [5] Dielectric spectrum and structure of aqueous solutions of dimethyl sulfoxide
    Verstakov, E. S.
    Korobkova, S. A.
    Nosaeva, T. A.
    RUSSIAN CHEMICAL BULLETIN, 2020, 69 (02) : 255 - 259
  • [6] Features of light scattering in aqueous solutions of dimethyl sulfoxide
    M. N. Rodnikova
    Yu. A. Zakharova
    I. A. Solonina
    D. A. Sirotkin
    Russian Journal of Physical Chemistry A, 2012, 86 : 892 - 894
  • [7] MECHANISMS OF NUCLEOPHILIC DISPLACEMENT IN AQUEOUS DIMETHYL SULFOXIDE SOLUTIONS
    FUCHS, R
    BLOOMFIELD, JJ
    MCCRARY, GE
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (20) : 4281 - &
  • [8] Dielectric spectrum and structure of aqueous solutions of dimethyl sulfoxide
    E. S. Verstakov
    S. A. Korobkova
    T. A. Nosaeva
    Russian Chemical Bulletin, 2020, 69 : 255 - 259
  • [9] Features of light scattering in aqueous solutions of dimethyl sulfoxide
    Rodnikova, M. N.
    Zakharova, Yu. A.
    Solonina, I. A.
    Sirotkin, D. A.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 86 (05) : 892 - 894
  • [10] NONTRADITIONAL ANALYTICAL PROPERTIES OF CYANIDE COMPLEXES OF METALS IN AQUEOUS DIMETHYL-SULFOXIDE SOLUTIONS
    KUZNETSOV, VV
    KORCHAGINA, OA
    JOURNAL OF ANALYTICAL CHEMISTRY, 1992, 47 (02) : 218 - 225