A novel mixed-valence copper coordination polymer: synthesis, characterization and crystal structure

被引：11

作者：

Fan, Guang ^{[1
]}

Xie, Gang ^{[1
]}

Chen, Sanping ^{[1
]}

Gao, Shengli ^{[1
]}

Shi, Qizhen ^{[1
]}

机构：

[1] NW Univ Xian, Dept Chem, Shaanxi Key Lab Phys Inorgan Chem, Xian 710069, Shaanxi, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2006年 / 59卷 / 07期

关键词：

hydrothermal reaction; copper; 2-pyrazinecarboxylic acid; mixed-valency; coordination polymer; crystal structure;

D O I：

10.1080/00958970500376229

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal reaction of copper(II) nitrate trihydrate with 2-pyrazinecarboxylic acid in the presence of phosphorous acid gave a novel mixed-valence coordination polymer, [Cu(I)Cu(II)(C5H3N2O2)(2)(NO3)(H2O)](n) ( 1), which has been structurally characterized. Crystal data: triclinic, P(1) over bar, a = 6.2266(6), b = 8.0148(7), c = 14.443(1) angstrom, alpha = 74.698(1), beta = 84.865(1), gamma = 84.532(1)degrees, V = 690.51(11) angstrom(3), Z = 2, R-1 = 0.0262. The complex features linear -Cu(1)(2-pyrazinecarboxylate)-Cu(2)-(NO3)(H2O)(2- pyrazinecarboxylate)-Cu(3)(2-pyrazinecarboxylate)-Cu(2)(NO3)(H2O)(2-pyrazinecarboxylate)- strands cross-linked by water molecules to form a two-dimensional sheet, further connected by intralayer Cu(2)center dot center dot center dot NO3- interactions to form a novel cavity. Other characteristic data are given.

引用

页码：791 / 795

页数：5

共 18 条

[1]

[Anonymous], 1995, Transition Metal Oxides: An Introduction to Their Electronic Structure and Properties

[2]

Ciurtin D. M., 2003, J CHEM SOC DA, P1245

[3]

Ciurtin DM, 2002, ABSTR PAP AM CHEM S, V223, pA58

[4] A new mixed-metal Ag-Co coordination polymer assembled from cobalt-containing molecular building blocks and AgNO3 [J].

Ciurtin, DM ;

Smith, MD ;

zur Loye, HC .

SOLID STATE SCIENCES, 2002, 4 (04) :461-465

[5]

Dong YB, 2000, ANGEW CHEM INT EDIT, V39, P4271, DOI 10.1002/1521-3773(20001201)39:23<4271::AID-ANIE4271>3.0.CO

[6]

2-1

[7] Novel M(II)-Hg(II) coordination polymers generated from metal-containing building blocks M(2-pyrazinecarboxylate)2 • (H2O)2 (M = Cu, Ni, Co) and HgCl2 [J].

Dong, YB ;

Smith, MD ;

zur Loye, HC .

SOLID STATE SCIENCES, 2000, 2 (08) :861-870

[8]

DONG YB, 2000, SOLID STATE SCI, V2, P225

[9]

FALCKER JP, 1992, ENCY INORGANIC CHEM

[10]

Karlin K.D., 1986, BIOL INORGANIC COPPE

← 1 2 →