Light-induced stereospecific intramolecular [2+2]-cycloaddition of atropisomeric 3,4-dihydro-2-pyridones

被引：22

作者：

Kumarasamy, Elango ^{[1
]}

Sivaguru, J. ^{[1
]}

机构：

[1] N Dakota State Univ, Dept Chem & Biochem, Fargo, ND 58108 USA

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 39期

基金：

美国国家科学基金会;

关键词：

PHOTOCHEMICAL-REACTIONS; STEREOSELECTIVITY; CHIRALITY; AMIDES;

D O I：

10.1039/c2cc37123e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Atropisomeric 3,4-dihydro-2-pyridones undergo stereospecific [2+2]-photocycloaddition in solution with high stereoselectivity (ee > 98% and de > 96%) in the product. The chiral transfer during phototransformation was rationalized based on the stability/reactivity of the biradical.

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收藏

页码：4346 / 4348

页数：3

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