Molecular Zinc Dihydride Stabilized by N-Heterocyclic Carbenes

被引：68

作者：

Rit, Arnab ^{[1
]}

Spaniol, Thomas P. ^{[1
]}

Maron, Laurent ^{[2
,3
]}

Okuda, Jun ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Inorgan Chem, D-52056 Aachen, Germany

[2] Univ Toulouse, F-31077 Toulouse, France

[3] UPS, CNRS UMR LPCNO 5215, CNRS, INSA, F-31077 Toulouse, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 17期

关键词：

carbon dioxide; homogeneous catalysis; hydrides; N-heterocyclic carbenes; zinc; METHANOL SYNTHESIS; MAGNESIUM HYDRIDE; CRYSTAL-STRUCTURE; CARBON-DIOXIDE; X-RAY; REACTIVITY; ZN; GENERATION; CATALYSTS; HYDROZINCATION;

D O I：

10.1002/anie.201300749

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solubility problems solved: The first examples of discrete soluble zinc dihydride adducts with NHC ligands reacted with CO2 to produce formate species and efficiently catalyzed the dehydrocoupling of silanes with methanol. These compounds were characterized both in solution and in the solid state (see picture). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4664 / 4667

页数：4

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