A simple corresponding-states group-contribution method for estimating surface tension of ionic liquids

被引：51
作者：
Wu, Ke-Jun [1 ]
Zhao, Chun-Xia [1 ]
He, Chao-Hong [1 ]
机构：
[1] Zhejiang Univ, State Key Lab Chem Engn, Dept Chem & Biol Engn, Hangzhou 310027, Peoples R China
来源：
FLUID PHASE EQUILIBRIA | 2012年 / 328卷
关键词：
Corresponding-states group-contribution method; Surface tension; Ionic liquids; PHYSICAL-PROPERTIES; THERMOPHYSICAL PROPERTIES; TEMPERATURE-DEPENDENCE; PHYSICOCHEMICAL PROPERTIES; BINARY-MIXTURES; 0.1; MPA; DENSITY; ANION; PURE; TETRAFLUOROBORATE;
D O I：
10.1016/j.fluid.2012.05.021
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A corresponding-states group-contribution method is proposed to estimate the surface tension of ionic liquids covering wide ranges of temperature (268.29-533.20 K) and surface tension (15.50-76.20 mN/m) based on experimental data collected from literatures. A good agreement between the predicted and experimental data from literature was obtained for total 1224 data points of 105 ionic liquids with an average absolute deviation (AAD) of 4.95%. The corresponding-states group-contribution method developed in this paper offers a simple but reliable approach for estimating surface tension of new ionic liquids in wide ranges of temperature at atmospheric pressure. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：42 / 48
页数：7
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