Splitting of dihydrogen by five-membered zirconacycloallenoids: a novel pathway to conjugated diene zirconocene complexes

被引：15

作者：

Bender, Georg ^{[1
]}

Kehr, Gerald ^{[1
]}

Daniliuc, Constantin G. ^{[1
]}

Dao, Quang Minh ^{[2
]}

Ehrlich, Stephan ^{[2
]}

Grimme, Stefan ^{[2
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

[2] Univ Bonn, Inst Phys & Theoret Chem, Mulliken Ctr Theoret Chem, D-53115 Bonn, Germany

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 90期

关键词：

HYDROGEN-TRANSFER; TRANSFORMATION; ACTIVATION; ZIRCONIUM; ALCOHOLS; DESIGN;

D O I：

10.1039/c2cc36189b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The five-membered zirconacycloallenoids 2 react rapidly with dihydrogen under mild conditions to yield the corresponding (s-cis-conjugated diene)zirconocenes 3. The reaction involves splitting of the H-2 molecule between the metal center and a ligand carbon atom.

引用

页码：11085 / 11087

页数：3

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