On the reactivity of o-lithloaryl ethers:: Tandem anion translocation and Wittig rearrangement

被引：48

作者：

Barluenga, J

Fañanás, FJ

Sanz, R

Marcos, C

Trabada, M

机构：

[1] Univ Oviedo, Inst Univ Quim Organomet Enrique Mol, Unidad Asociada, CSIC, Oviedo 33071, Spain

[2] Univ Burgos, Fac Ciencias, Dept Quim, Area Quim Organ, Burgos 09001, Spain

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 09期

关键词：

D O I：

10.1021/ol0258029

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allyl and benzyl 2-lithloaryl ethers, generated by bromine-lithium exchange in THF, undergo a new tandem anion translocation-[1,2]-Wittig rearrangement allowing the isolation of the corresponding benzylic alcohols.

引用

页码：1587 / 1590

页数：4

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