Synthesis and characterisation of functional manganese doped ZnS quantum dots for bio-imaging application

被引:10
作者
Singhal, Manju [1 ]
Sharma, J. K. [1 ]
Jeon, H. C. [2 ]
Kang, T. W. [2 ]
Kumar, Sunil [2 ]
机构
[1] Maharishi Markandeshwar Univ, Dept Phys, Ambala, India
[2] Dongguk Univ, Nano Informat Technol Acad, Seoul 100715, South Korea
基金
新加坡国家研究基金会;
关键词
ZnS:Mn; quantum dots; glutathione; photoluminescence; biological window; GLUTATHIONE; FLUORESCENCE; PHOTOLUMINESCENCE; SENSOR;
D O I
10.1080/17436753.2019.1587937
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Fluorescent quantum dots (QDs) are potential candidates for bio-imaging but major problems in using them for bio-imaging applications are either bandgap lying in UV region or the cytotoxicity of the visible light-excited cadmium-based QDs. Keeping these things in mind, glutathione (GLT) functionalised Mn-doped ZnS QDs has been studied to make a desired fluorescent system forbioimaging application. XRD measurements show that grain size decreases at higher concentration of GLT capping on Mn-doped quantum dots. UV-visible studies show that the band gap shows a blue shift at higher GLT concentration. FTIR studies confirm GLT functionalisation on the surface of ZnS QDs. Both UV excited and IR excited photoluminescence spectrum of samples exhibited a tunable orange emission intensity with increase in GLT concentration however multiphoton infrared excited spectra was used to show the feasibility of GLT functionalised ZnS:Mn quantum dots for a real application in a biological window of 650-950nm.
引用
收藏
页码:321 / 328
页数:8
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