First synthesis of 1,1′-ferrocene bis-aminophosphonic esters

被引：8

作者：

Lewkowski, J ^{[1
]}

Rzezniczak, M ^{[1
]}

Skowronski, R ^{[1
]}

机构：

[1] Univ Lodz, Dept Organ Chem, PL-90136 Lodz, Poland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 07期

关键词：

1,1'-ferrocenedicarboxaldehyde; Schiff bases; aminophosphonates; asymmetrical induction; 1,1'-bis-substituted ferrocene moiety;

D O I：

10.1016/j.jorganchem.2004.01.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The series of aminophosphonates bearing the 1,1'-bis-substituted ferrocenyl moiety was obtained by the addition of dialkyl phosphites to an azomethine bond of Schiff bases derived from 1,1'-ferrocene-bis-carboxaldehyde. This addition led to both diastereoisomeric forms demonstrating its behaviour to be contrary to the addition to terephthalic Schiff bases, which led exclusively to a meso-form. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1265 / 1270

页数：6

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