Synthesis and Photochromism Studies of 1-[2-methyl-5-(2-methoxylphenyl)-3-thienyl]-2-[2-methyl-(5-ethynyl)trimethylsilane-3-thienyl]perfluorocyclopentene

被引：0

作者：

Lu, R. M. ^{[1
]}

Tian, Z. Y. ^{[1
]}

Cui, S. Q. ^{[1
]}

Pu, S. Z. ^{[1
]}

机构：

[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China

来源：

3RD INTERNATIONAL CONFERENCE ON ADVANCED COMPOSITE MATERIALS AND MANUFACTURING ENGINEERING (CMME 2015) | 2015年

关键词：

Diarylethene; Photochromism; Fluorescence; DIARYLETHENE; SWITCHES;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A photochromic A new unsymmetrical photochromic diarylethene compound, 1-[2-methyl-5-(2-methoxylphenyl)-3-thienyl]-2-[2-methyl-(5-ethynyl)trimethylsilane-3-thienyl] perfluorocyclopentene (1a) was synthesized, and its photochromic reactivity, fluorescent were also investigated. The result indicated that the diarylethene 1a changed the color from colorless to blue upon irradiation with 297 nm UV light.

引用

页码：64 / 67

页数：4

共 13 条

[1] Study on photochromism of diarylethenes with a 2,5-dihydropyrrole bridging unit: A convenient preparation of 3,4-diarylpyrroles from 3,4-diaryl-2,5-dihydropyrroles [J].

Chen, Y ;

Zeng, DX ;

Xie, N ;

Dang, YZ .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (13) :5001-5005

[2] Temperature gating of the ring-opening process in diarylethene molecular switches [J].

Dulic, Diana ;

Kudernac, Tibor ;

Puzys, Audrius ;

Feringa, Ben L. ;

van Wees, Bart J. .

ADVANCED MATERIALS, 2007, 19 (19) :2898-+

[3] Substituent position effect on the properties of new unsymmetrical isomeric diarylethenes having a chlorine atom [J].

Fan, Congbin ;

Pu, Shouzhi ;

Liu, Gang ;

Yang, Tianshe .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2008, 197 (2-3) :415-425

[4] Digital photoswitching of fluorescence based on the photochromism of diarylethene derivatives at a single-molecule level [J].

Fukaminato, T ;

Sasaki, T ;

Kawai, T ;

Tamai, N ;

Irie, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (45) :14843-14849

[5] Photochromism: Memories and switches - Introduction [J].

Irie, M .

CHEMICAL REVIEWS, 2000, 100 (05) :1683-1683

[6] Reversible conductance switching of single diarylethenes on a gold surface [J].

Katsonis, Nathalie ;

Kudernac, Tibor ;

Walko, Martin ;

van der Molen, Sense Jan ;

van Wees, Bart J. ;

Feringa, Ben L. .

ADVANCED MATERIALS, 2006, 18 (11) :1397-+

[7] Photochromism of 1,2-bis(2-methyl-6-nitro-1-benzothiophen-3-yl) perfluorocyclopentene in a single-crystalline phase: Dichroism of the closed-ring form isomer [J].

Kobatake, S ;

Yamada, M ;

Yamada, T ;

Irie, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (37) :8450-8456

[8] Photoresponsive Ion Extraction/Release Systems: Dynamic Ion Optodes for Calcium and Sodium Based on Photochromic Spiropyran [J].

Mistlberger, Guenter ;

Xie, Xiaojiang ;

Pawlak, Marcin ;

Crespo, Gaston A. ;

Bakker, Eric .

ANALYTICAL CHEMISTRY, 2013, 85 (05) :2983-2990

[9] Photochromic diarylethene for two-photon 3D optical storage [J].

Pu, Shouzhi ;

Tang, Huohong ;

Chen, Bing ;

Xu, Jingkun ;

Huang, Wenhao .

MATERIALS LETTERS, 2006, 60 (29-30) :3553-3557

[10] The effect of substituent position upon unsymmetrical isomeric diarylethenes bearing a methoxy group [J].

Pu, Shouzhi ;

Fan, Congbin ;

Miao, Wenjuan ;

Liu, Gang .

DYES AND PIGMENTS, 2010, 84 (01) :25-35

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