Improving the hydrogen storage properties of MgH2 by reversibly forming Mg-Al solid solution alloys

被引：60

作者：

Zhong, H. C. ^{[1
]}

Wang, H. ^{[2
]}

Ouyang, L. Z. ^{[2
]}

机构：

[1] Xiamen Univ Technol, Dept Mat Sci & Engn, Xiamen 361024, Peoples R China

[2] S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2014年 / 39卷 / 07期

关键词：

Mg(Al) solid solution; Hydrogen storage properties; Phase transition; Ball milling; HIGH-CAPACITY; MAGNESIUM; DESORPTION;

D O I：

10.1016/j.ijhydene.2013.12.074

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Supersaturated Mg(Al) solid solutions with reduced lattice constants were successfully prepared by ball milling Mg and Al powder mixtures. The microstructure and phase transition were investigated by XRD. The results indicated that disproportionation of supersaturated Mg(Al) solid solution to MgH2 and Al was caused by hydrogenation, then equilibrium Mg(Al) solid solution formed after dehydrogenation, while the intermetallic compound Mg17Al12 reversibly decomposed to MgH2 and intermediate phase Al3Mg2 which could further decompose to MgH2 and Al by hydriding. These reversible phase transitions make Mg-Al alloys show an observably lowered de/hydriding enthalpy and activation energy in comparison with pure Mg. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights

引用

页码：3320 / 3326

页数：7

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