Sulfite oxidation: The state-of-the-art of the problem

被引：0

作者：

Ermakov, AN ^{[1
]}

Poskrebyshev, GA ^{[1
]}

Purmal, AP ^{[1
]}

机构：

[1] NN SEMENOV CHEM PHYS INST,MOSCOW 117977,RUSSIA

来源：

KINETICS AND CATALYSIS | 1997年 / 38卷 / 03期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This review is devoted to the analysis of the kinetics of S(IV) (sulfite and bisulfite ions) oxidation by molecular oxygen, ozone, hydrogen peroxide, and peroxymonosulfate in aqueous solutions. Much attention is given to S(IV) oxidation by oxygen. On the basis of the analysis performed, the most reliable rate constants of the reactions involved in the chain-radical process are selected. The ion-molecular mechanism of S(IV) oxidation by H2O2 is considered. This mechanism is shown to closely resemble that of S(IV) oxidation by peroxymonosulfate. Analysis of sulfite oxidation by ozone leads to the conclusion that, in spite of a great number of studies, the mechanism of this reaction remains unclear.

引用

页码：295 / 308

页数：14

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