Early transition metal thiolates

被引:119
作者
Stephan, DW
Nadasdi, TT
机构
[1] Dept. of Chemistry and Biochemistry, University of Windsor, Windsor
关键词
early transition metal thiolates; synthesis; chemistry;
D O I
10.1016/0010-8545(95)01134-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This article presents a comprehensive and systematic review of the syntheses, structures and reactivities of thiolate complexes of group 4 and 5 metals (i.e. Ti, Zr, Hf, V, Nb and Ta). This includes a discussion of monometallic and polymetallic species as well as recent advances in heterobimetallic derivatives. Specifically excluded are dithiolene derivatives of the early metals as these compounds have been previously reviewed.
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页码:147 / 208
页数:62
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