Nickel-Catalysed Hydroalkoxylation Reaction of 1,3-Butadiene: Ligand Controlled Selectivity for the Efficient and Atom-Economical Synthesis of Alkylbutenyl Ethers

被引：19
作者：
Bigot, Sandra [1 ]
Ibn El Alami, Mohammed Samir [1 ]
Mifleur, Alexis [1 ]
Castanet, Yves [1 ]
Suisse, Isabelle [1 ]
Mortreux, Andre [1 ]
Sauthier, Mathieu [1 ]
机构：
[1] Univ Lille Nord France, UCCS, ENSCL, F-59652 Villeneuve Dascq, France
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 30期
关键词：
butadiene; ethers; homogeneous catalysis; hydroalkoxylation; nickel; LINEAR DIMERIZATION; TELOMERIZATION; BUTADIENE; CYCLODIMERIZATION; 1,3-DIENES; COMPLEXES;
D O I：
10.1002/chem.201300633
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The nickel-catalysed hydroalkoxylation of butadiene is promoted by a nickel(0)/dppb catalyst (dppb=1,4-bis(diphenylphosphino)butane; see scheme). By following this new synthetic procedure, alkylbutenyl ethers are readily obtained from an alcohol and 1,3-butadiene with exclusion of dimerisation and telomerisation products. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：9785 / 9788
页数：4
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