Nitrogen NMR spectroscopy of metal nitrosyls and related compounds

被引：73
作者：
Mason, J
Larkworthy, LF
Moore, EA
机构：
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
[2] Open Univ, Dept Chem, Milton Keynes MK7 6AA, Bucks, England
[3] Univ Surrey, Dept Chem, Guildford GU2 5XH, Surrey, England
来源：
CHEMICAL REVIEWS | 2002年 / 102卷 / 04期
关键词：
D O I：
10.1021/cr000075l
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An overview is given on the use of nitrogen NMR spectroscopy to study metal nitrosyls and related compounds. Topics discussed include the preparation of 15N-enriched metal nitrosyls, patterns of nitrogen shifts in metal nitrosyls and related compounds, nitrogen shielding tensors in linear nitrosyls and related compounds, theoretical studies of nitrogen shielding tensors in metal nitrosyls and related compounds, patterns of spin-spin couplings in nitrosyls and related compounds, and dynamic processes observed in nitrogen resonance.
引用
收藏
页码：913 / 934
页数：22
相关论文
共 180 条
[51]   EFFECT OF ELECTRON LONE-PAIRS ON NUCLEAR-SPIN SPIN COUPLING-CONSTANTS [J].
GIL, VMS ;
VONPHILIPSBORN, W .
MAGNETIC RESONANCE IN CHEMISTRY, 1989, 27 (05) :409-430
[52]   N-14 QUADRUPOLE COUPLING CONSTANT OF CYANOGEN CHLORIDE IN LIQUID PHASE [J].
GILLEN, KT ;
NOGGLE, JH .
JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (09) :4905-&
[53]   C-13 NMR CHEMICAL-SHIFT TENSORS OF METAL-CARBONYLS [J].
GLEESON, JW ;
VAUGHAN, RW .
JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (09) :5384-5392
[54]   Solid-state NMR, Mossbauer, crystallographic, and density functional theory investigation of Fe-O2 and Fe-O2 analogue metalloporphyrins and metalloproteins [J].
Godbout, N ;
Sanders, LK ;
Salzmann, R ;
Havlin, RH ;
Wojdelski, M ;
Oldfield, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (16) :3829-3844
[55]   TEMPERATURE-DEPENDENCE OF N-14 QUADRUPOLE COUPLING-CONSTANT IN SODIUM-NITRATE AS STUDIED BY NMR ON A SINGLE-CRYSTAL [J].
GOURDJI, M ;
PENEAU, A ;
GUIBE, L .
JOURNAL DE PHYSIQUE, 1974, 35 (06) :497-508
[56]  
GOURDJI M, 1965, CR HEBD ACAD SCI, V260, P1131
[57]   N-15 NMR OF STABLE NITROXIDES [J].
GRIGOREV, IA ;
VOLODARSKY, LB ;
GOGOLEV, AZ ;
SAGDEEV, RZ .
CHEMICAL PHYSICS LETTERS, 1985, 122 (1-2) :46-50
[58]   SWINGING OF THE BENT NITROSYL LIGAND IN [CO((NO)-N-15)(TPP)] - A SOLID-STATE MOTION DETECTED BY N-15 CPMAS NMR-SPECTROSCOPY [J].
GROOMBRIDGE, CJ ;
LARKWORTHY, LF ;
MASON, J .
INORGANIC CHEMISTRY, 1993, 32 (04) :379-380
[59]   SYNTHESIS AND N-15 NUCLEAR-MAGNETIC-RESONANCE SHIFT TENSORS OF BENT NITROSYL COMPLEXES WITH N-SUBSTITUTED SALICYLIDENEIMINATE COLIGANDS - THE SHIFT TENSOR AS A CRITERION OF MNO BOND ANGLE [J].
GROOMBRIDGE, CJ ;
LARKWORTHY, LF ;
MARECAUX, A ;
POVEY, DC ;
SMITH, GW ;
MASON, J .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (21) :3125-3131
[60]   APPLICATIONS OF NATURAL-ABUNDANCE NITROGEN-15 NUCLEAR MAGNETIC-RESONANCE TO LARGE BIOCHEMICALLY IMPORTANT MOLECULES [J].
GUST, D ;
MOON, RB ;
ROBERTS, JD .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1975, 72 (12) :4696-4700
12345678910