Nitrogen NMR spectroscopy of metal nitrosyls and related compounds

被引:73
作者
Mason, J
Larkworthy, LF
Moore, EA
机构
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
[2] Open Univ, Dept Chem, Milton Keynes MK7 6AA, Bucks, England
[3] Univ Surrey, Dept Chem, Guildford GU2 5XH, Surrey, England
关键词
D O I
10.1021/cr000075l
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An overview is given on the use of nitrogen NMR spectroscopy to study metal nitrosyls and related compounds. Topics discussed include the preparation of 15N-enriched metal nitrosyls, patterns of nitrogen shifts in metal nitrosyls and related compounds, nitrogen shielding tensors in linear nitrosyls and related compounds, theoretical studies of nitrogen shielding tensors in metal nitrosyls and related compounds, patterns of spin-spin couplings in nitrosyls and related compounds, and dynamic processes observed in nitrogen resonance.
引用
收藏
页码:913 / 934
页数:22
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