Comment on "Bi-functional Li2B12H12 for energy storage and conversion applications: solid-state electrolyte and luminescent down-conversion dye" by J. A. Teprovich Jr, H. Colon-Mercado, A. L. Washington II, P. A. Ward, S. Greenway, D. M. Missimer, H. Hartman, J. Velten, J. H. Christian and R. Zidan, J-Mater. Chem. A, 2015, 3, 22853

被引：6

作者：

Paskevicius, M. ^{[1
,2
,3
]}

Jakobsen, A. S. ^{[1
,2
]}

Bregnhoj, M. ^{[1
,2
]}

Hansen, B. R. S. ^{[1
,2
]}

Moller, K. T. ^{[1
,2
,3
]}

Ogilby, P. R. ^{[1
,2
]}

Jensen, T. R. ^{[1
,2
]}

机构：

[1] Aarhus Univ, Interdisciplinary Nanosci Ctr, Ctr Mat Crystallog, Langelandsgade 140, DK-8000 Aarhus C, Denmark

[2] Aarhus Univ, Dept Chem, Langelandsgade 140, DK-8000 Aarhus C, Denmark

[3] Curtin Univ, Fuels & Energy Technol Inst, Dept Phys & Astron, Wark Ave, Bentley, WA 6102, Australia

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2019年 / 7卷 / 08期

基金：

澳大利亚研究理事会;

关键词：

Boron compounds;

D O I：

10.1039/c8ta10735a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photoluminescent properties of selected metal closo-boranes have been assessed. Group 3 elements Sc, Y, and La as well as Li, Na, and Eu-based B10H102- and B12H122- compounds displayed photoluminescence in the ultraviolet (emission lambda(max) = 350 nm) that was not visible to the human eye, in contrast to previous reports. We attribute these earlier results to arachno-borane impurities, which are more readily observed due to their longer wavelength emission spectra.

引用

页码：4185 / 4187

页数：3

共 2 条

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