Synthesis, polymerization and conducting properties of an ionic liquid-type anionic monomer

被引：29
|
作者：
Juger, Jonathan [1 ]
Meyer, Franck [1 ]
Vidal, Frederic [1 ]
Chevrot, Claude [1 ]
Teyssie, Dominique [1 ]
机构：
[1] Univ Cergy Pontoise, Lab Physicochim Polymeres & Interfaces, F-95031 Cergy Pontoise, France
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 01期
关键词：
NETWORKS;
D O I：
10.1016/j.tetlet.2008.10.096
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of a new ionic liquid-type monomer has been performed by association of a methacrylate polymerizable group, a polar tri(ethylene oxide) (TEO) spacer, a trifluoromethane sulfonic (TFSI-) anion and a free imidazolium (EMIm(+)) cation. The ionic liquid monomer (ILM) has demonstrated a good thermal stability and a high ionic conductivity around 2.1 X 10(-3) S cm(-1) at 20 degrees C. The corresponding homopolymer has shown an ionic conductivity closely related to the monomer (6.5 x 10(-4) S cm(-1) at 20 degrees C, which confirms the ILM as a valuable monomer for the formation of polymeric ionic liquid (PIL) materials. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：128 / 131
页数：4
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