Bimetallic NiFe2O4 synthesized via confined carburization in NiFe-MOFs for efficient oxygen evolution reaction

被引:21
作者
Fang, Zhiqiang [1 ]
Hao, Zhaomin [1 ]
Dong, Qingsong [1 ]
Cui, Yong [2 ]
机构
[1] Henan Univ, Coll Chem & Chem Engn, Henan Key Lab Polyoxometalate Chem, Kaifeng, Henan, Peoples R China
[2] Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety Assessment, Div Mat Special Environm, Shenyang, Liaoning, Peoples R China
基金
中国国家自然科学基金;
关键词
Metal oxides; Particles; Nanosize; X-ray techniques; Oxygen evolution reaction; Electrochemical applications; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMERS; WATER; OXIDE; ELECTROCATALYSTS; HYDROGEN; NANOSHEETS; NANORODS; POLYANILINE; REDUCTION;
D O I
10.1007/s11051-018-4209-3
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Transition metal oxides that derived from metal-organic framework (MOF) precursor have intensively received attention because of their numerous electrochemical applications. Bimetallic Ni-Fe oxides have been rarely reported on the basis of MOF-related strategy. Herein, a bimetallic NiFe2O4 was successfully synthesized via confined carburization in NiFe-MOF precursors and characterized by XRD, XPS, SEM, and TEM. After conducting an investigation of oxygen evolution reaction (OER), the as-synthesized NiFe2O4 material exhibited good catalytic efficiency and high stability and durability in alkaline media. The as-synthesized NiFe2O4 material would promote the development of MOFs in non-noble-metal OER catalyst.
引用
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页数:10
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