An Amorphous Red Phosphorus/Carbon Composite as a Promising Anode Material for Sodium Ion Batteries

被引：812

作者：

Kim, Youngjin ^{[1
]}

Park, Yuwon ^{[1
,2
,3
]}

Choi, Aram ^{[2
,3
]}

Choi, Nam-Soon ^{[2
,3
]}

Kim, Jeongsoo ^{[4
]}

Lee, Junesoo ^{[4
]}

Ryu, Ji Heon ^{[5
]}

Oh, Seung M. ^{[1
]}

Lee, Kyu Tae ^{[2
,3
]}

机构：

[1] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151742, South Korea

[2] Ulsan Natl Inst Sci & Technol, Interdisciplinary Sch Green Energy, Ulsan 689798, South Korea

[3] Ulsan Natl Inst Sci & Technol, KIER UNIST Adv Ctr Energy, Ulsan 689798, South Korea

[4] SK Innovat Co, Taejon 305712, South Korea

[5] Korea Polytech Univ, Grad Sch Knowledge Based Technol & Energy, Gyeonggi 429793, South Korea

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 22期

基金：

新加坡国家研究基金会;

关键词：

electrochemistry; sodium ion batteries; anode material; phosphorus; composite; HIGH-CAPACITY; LI-ION; NEGATIVE ELECTRODES; BLACK PHOSPHORUS; CARBON; STORAGE; PERFORMANCE; CHALLENGES; TEREPHTHALATE; POLYACRYLATE;

D O I：

10.1002/adma.201204877

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An amorphous red phosphorus/carbon composite is obtained through a facile and simple ball milling process, and its electrochemical performance as an anode material for Na ion batteries is evaluated. The composite shows excellent electrochemical performance including a high specific capacity of 1890 mA h g-1, negligible capacity fading over 30 cycles, an ideal redox potential (0.4 V vs. Na/Na+), and an excellent rate performance, thus making it a promising candidate for Na ion batteries. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3045 / 3049

页数：5

共 42 条

[1] Nanomaterials for rechargeable lithium batteries [J].

Bruce, Peter G. ;

Scrosati, Bruno ;

Tarascon, Jean-Marie .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946

[2] Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications [J].

Cao, Yuliang ;

Xiao, Lifen ;

Sushko, Maria L. ;

Wang, Wei ;

Schwenzer, Birgit ;

Xiao, Jie ;

Nie, Zimin ;

Saraf, Laxmikant V. ;

Yang, Zhengguo ;

Liu, Jun .

NANO LETTERS, 2012, 12 (07) :3783-3787

[3] Challenges for Na-ion Negative Electrodes [J].

Chevrier, V. L. ;

Ceder, G. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (09) :A1011-A1014

[4] Better Cycling Performances of Bulk Sb in Na-Ion Batteries Compared to Li-Ion Systems: An Unexpected Electrochemical Mechanism [J].

Darwiche, Ali ;

Marino, Cyril ;

Sougrati, Moulay T. ;

Fraisse, Bernard ;

Stievano, Lorenzo ;

Monconduit, Laure .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (51) :20805-20811

[5] A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries [J].

Ellis, B. L. ;

Makahnouk, W. R. M. ;

Makimura, Y. ;

Toghill, K. ;

Nazar, L. F. .

NATURE MATERIALS, 2007, 6 (10) :749-753

[6] Sodium and sodium-ion energy storage batteries [J].

Ellis, Brian L. ;

Nazar, Linda F. .

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2012, 16 (04) :168-177

[7] Positive Electrode Materials for Li-Ion and Li-Batteries [J].

Ellis, Brian L. ;

Lee, Kyu Tae ;

Nazar, Linda F. .

CHEMISTRY OF MATERIALS, 2010, 22 (03) :691-714

[8] PRESSURE-DEPENDENCE OF THE ELECTRICAL-CONDUCTIVITY OF AMORPHOUS RED PHOSPHORUS [J].

EXTANCE, P ;

ELLIOTT, SR .

PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1981, 43 (03) :469-483

[9] Superior Electrochemical Performance and Storage Mechanism of Na3V2(PO4)3 Cathode for Room-Temperature Sodium-Ion Batteries [J].

Jian, Zelang ;

Han, Wenze ;

Lu, Xia ;

Yang, Huaixin ;

Hu, Yong-Sheng ;

Zhou, Jing ;

Zhou, Zhibin ;

Li, Jianqi ;

Chen, Wen ;

Chen, Dongfeng ;

Chen, Liquan .

ADVANCED ENERGY MATERIALS, 2013, 3 (02) :156-160

[10] Lithium Storage ion Carbon Nanostructures [J].

Kaskhedikar, Nitin A. ;

Maier, Joachim .

ADVANCED MATERIALS, 2009, 21 (25-26) :2664-2680

← 1 2 3 4 5 →