Sulfonyl-1,2,3-Triazoles: Convenient Synthones for Heterocyclic Compounds

被引：202

作者：

Zibinsky, Mikhail ^{[1
]}

Fokin, Valery V. ^{[1
]}

机构：

[1] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 05期

基金：

美国国家科学基金会;

关键词：

carbenes; imidazoles; oxazolines; rhodium; triazoles; RH-CATALYZED TRANSANNULATION; CYCLOADDITION; ALKYNES; CYCLOPROPANATION; HYDROSILYLATION; REACTIVITY; OXAZOLINES; LIGANDS;

D O I：

10.1002/anie.201206388

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As easy as 1,2,3: Readily available and shelf-stable 1-sulfonyl-1,2,3- triazoles react with aldehydes and aldimines in the presence of RhII catalysts to produce 4-oxazolines and 1,2,5-trisubstituted imidazoles (see scheme). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1507 / 1510

页数：4

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