Comment on "The Debye-Huckel theory and its importance in modeling electrolyte solutions"

被引：8

作者：

Shilov, Ignat Yu. ^{[1
]}

Lyashchenko, Andrey K. ^{[2
]}

机构：

[1] Lomonosov Moscow State Univ, Dept Chem, Moscow 119991, Russia

[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

FLUID PHASE EQUILIBRIA | 2019年 / 485卷

基金：

俄罗斯基础研究基金会;

关键词：

Debye-Huckel theory; Born theory; Electrolyte solution; Modeling; Permittivity; Solvation; DEPENDENT STATIC PERMITTIVITY; DIELECTRIC-DISPERSION; ACTIVITY-COEFFICIENTS; AQUEOUS-SOLUTIONS; FRICTION; WATER; NABR;

D O I：

10.1016/j.fluid.2018.12.019

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

In a recent review by Kontogeorgis et al. [Fluid Phase Equilib. 462 (2018) 130-152] many debatable issues concerning the Debye-Huckel theory and modeling electrolyte solutions are discussed. The goal of this comment is to complement this survey with a short summary of the extended Debye-Huckel theory [1.Yu. Shilov, A.K. Lyashchenko, 2015] which allows for an arbitrary variation of electrolyte solution static permittivity with concentration and thus sheds new light on the interrelation between the Debye-Huckel theory and the Born theory of solvation. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：248 / 250

页数：3

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