Oxidative Coupling of Terminal Rhenium Pnictide Complexes

被引：34

作者：

Abbenseth, Josh ^{[1
]}

Diefenbach, Martin ^{[2
]}

Hinz, Alexander ^{[3
]}

Alig, Lukas ^{[1
]}

Wuertele, Christian ^{[1
]}

Goicoechea, Jose M. ^{[4
]}

Holthausen, Max C. ^{[2
]}

Schneider, Sven ^{[1
]}

机构：

[1] Georg August Univ, Inst Anorgan Chem, Tammannstr 4, D-37077 Gottingen, Germany

[2] Goethe Univ, Inst Anorgan & Analyt Chem, Max von Laue Str 7, D-60438 Frankfurt, Germany

[3] Karlsruhe Inst Technol, Inst Inorgan Chem, Engesserstr 15, D-76131 Karlsruhe, Germany

[4] Univ Oxford, Dept Chem, Chem Res Lab, 12 Mansfield Rd, Oxford OX1 3TA, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 32期

基金：

欧洲研究理事会;

关键词：

dipnictides; pincer complexes; pnictides; QTAIM; rhenium; PHOSPHORUS; CHEMISTRY; DECARBONYLATION; ACTIVATION; REACTIVITY; ELEMENTS; LIGANDS; ROUTE; PAIR; P-2;

D O I：

10.1002/anie.201905130

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The isolation of rhenium(V) complexes with terminal phosphide and arsenide ligands was achieved upon decarbonylation of rhenium(III) pnictaethynolates. One-electron oxidation of the pnictide complexes yielded Pn-Pn (Pn=P, As) coupling products, which were spectroscopically and crystallographically characterized. Computational bond analysis suggests that these complexes are best described as {Pn(2)}(0) complexes that are stabilized by donor-acceptor interactions with the metal and a pyrazole ligand.

引用

页码：10966 / 10970

页数：5

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