catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2N:S]

被引：14

作者：

Khalaji, Aliakbar Dehno ^{[2
]}

Hadadzadeh, Hassan ^{[2
]}

Gotoh, Kazuma ^{[1
]}

Ishida, Hiroyuki ^{[1
]}

机构：

[1] Okayama Univ, Fac Sci, Dept Chem, Okayama 7008530, Japan

[2] Gorgan Univ Agr Sci & Nat Resources, Dept Sci, Gorgan 4918943464, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

ANIONS; ARRAYS;

D O I：

10.1107/S1600536808041925

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the cyrstal structure of the title compound, [Cu(NCS)(C18H20N2O2)](n) n, the Cu-I atom is coordinated in a distorted tetrahedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thiocyanate anions. The thiocyanate anion bridges the Cu-I atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E, E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)degrees.

引用

页码：M70 / U753

页数：11

共 10 条

[1] 1-D arrays of Cu(I)-Schiff base maintained by fourfold phenyl embraces isolating diiodocuprate(I) anions [J].

Amirnasr, M ;

Khalaji, AD ;

Falvello, LR .

INORGANICA CHIMICA ACTA, 2006, 359 (02) :713-717

[2]

Farrujia LJ., 1997, J APPL CRYSTALLOGR, V30, P565, DOI [10.1107/S0021889897003117, DOI 10.1107/S0021889897003117]

[3]

Higashi T., 1995, ABSCOR

[4]

Khalaji A.D., 2008, ANAL SCI, V24, px137

[5] Diacetonitrile[N,N′-bis(3,4,5-trimethoxybenzylidene) ethylenediamine] copper(I) perchlorate [J].

Khalaji, Aliakbar Dehno ;

Brad, Korbanjhon ;

Zhang, Yan .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M189-U1807

[6] 1D arrays of [Cu(Phca2en)2][AgI2] by fourfold phenyl embraces isolating diiodoargenate(I) anions [J].

Khalaji, Aliakbar Dehno ;

Welter, Richard .

INORGANICA CHIMICA ACTA, 2006, 359 (13) :4403-4406

[7]

*RIG MSC, 2004, CRYSTALSTRUCTURE PRO

[8] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[9] Single-crystal structure validation with the program PLATON [J].

Spek, AL .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :7-13

[10] catena-Poly[[(2,2′-bipyridine-κ2N,N′)copper(I)]-μ-cyanido-κ2C:N-[(2,2′-bipyridine-κ2N,N′)copper(I)]-μ-thiocyanato-κ2S:N] [J].

Zhao, Jun ;

Dong, Wen-Wen ;

Li, Dong-Sheng ;

He, Qiu-Fen .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M1576-U893

← 1 →