Solubility of Succinic Acid in Ethanol Plus Water Systems from 278.15 K to 333.15 K

被引：20

作者：

Hu, Yong-Hong ^{[1
,2
]}

Chen, Zhao-Guo ^{[1
]}

Yang, Wen-Ge ^{[1
]}

Shi, Ying ^{[1
]}

Sun, Hui-Ling ^{[2
]}

Li, Yong-Lan ^{[2
]}

机构：

[1] Nanjing Univ Technol, Coll Biotechnol & Pharmaceut Engn, Nanjing 210009, Jiangsu, Peoples R China

[2] Taiyuan Qiaoyou Chem Ind Co Ltd, Taiyuan 030025, Peoples R China

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2013年 / 42卷 / 01期

关键词：

Succinic acid; Solubility; Solid-liquid equilibrium; Correlation; MATHEMATICAL REPRESENTATION; THERMODYNAMIC PROPERTIES; METHANOL; MODEL; NIBS;

D O I：

10.1007/s10953-012-9951-z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In an equilibrium vessel, the solubilities of succinic acid in binary aqueous ethanol solvents were measured by the analytical stirred-flask method with the temperature ranging from 278.15 to 333.15 K at atmospheric pressure. Data on the corresponding solid-liquid equilibrium of succinic acid in binary aqueous ethanol solutions are essential for industrial design and further theoretical studies. The effect of solvent composition and temperature on the solubility is discussed. The solubility data were correlated with the Combined Nearly Ideal Binary Solvent/Redlich-Kister (CNIBS/R-K) model. The solubility measured in this study can be used for succinic acid purification or optical resolution by the preferential crystallization procedure.

引用

页码：102 / 110

页数：9

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