Thiacrown ether as regulator of lipase-catalyzed trans-esterification in organic media: Practical optical resolution of allyl alcohols

被引:40
作者
Takagi, Y
Teramoto, J
Kihara, H
Itoh, T
Tsukube, H
机构
[1] OKAYAMA UNIV,FAC EDUC,DEPT CHEM,OKAYAMA 700,JAPAN
[2] OSAKA CITY UNIV,FAC SCI,DEPT CHEM,OSAKA 558,JAPAN
关键词
D O I
10.1016/0040-4039(96)00991-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Thiacrown ether additive enhanced enantioselectivity in lipase-catalyzed trans-esterification of allyl alcohols. Small amounts of thiacrown ether offered highly enantioselective reaction when 5-phenylpentene-3-ol was subjected to the reaction of Pseudomonas cepacia lipase. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:4991 / 4992
页数:2
相关论文
共 5 条
[1]   LARGE ACTIVATION OF SERINE PROTEASES BY PRETREATMENT WITH CROWN-ETHERS [J].
BROOS, J ;
SAKODINSKAYA, IK ;
ENGBERSEN, JFJ ;
VERBOOM, W ;
REINHOUDT, DN .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (02) :255-256
[2]   QUANTITATIVE-ANALYSES OF BIOCHEMICAL KINETIC RESOLUTIONS OF ENANTIOMERS [J].
CHEN, CS ;
FUJIMOTO, Y ;
GIRDAUKAS, G ;
SIH, CJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (25) :7294-7299
[3]   Crown ethers as regulators of enzymatic reactions: Enhanced reaction rate and enantioselectivity in lipase-catalyzed hydrolysis of 2-cyano-1-methylethyl acetate [J].
Itoh, T ;
Takagi, Y ;
Murakami, T ;
Hiyama, Y ;
Tsukube, H .
JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (06) :2158-2163
[4]   ENHANCED REACTION-RATE AND ENANTIOSELECTIVITY IN LIPASE-CATALYZED HYDROLYSIS BY ADDITION OF A CROWN-ETHER [J].
ITOH, T ;
HIYAMA, Y ;
BETCHAKU, A ;
TSUKUBE, H .
TETRAHEDRON LETTERS, 1993, 34 (16) :2617-2620
[5]  
WONG CH, 1994, ENZYMES SYNTHETIC OR