Naturally Rolled-Up C/Si/C Trilayer Nanomembranes as Stable Anodes for Lithium-Ion Batteries with Remarkable Cycling Performance

被引：241

作者：

Deng, Junwen ^{[1
,2
]}

Ji, Hengxing ^{[3
]}

Yan, Chenglin ^{[1
]}

Zhang, Jiaxiang ^{[1
]}

Si, Wenping ^{[1
,2
]}

Baunack, Stefan ^{[1
]}

Oswald, Steffen ^{[4
]}

Mei, Yongfeng ^{[5
]}

Schmidt, Oliver G. ^{[1
,2
]}

机构：

[1] IFW Dresden, Inst Integrat Nanosci, D-01069 Dresden, Germany

[2] Tech Univ Chemnitz, D-09107 Chemnitz, Germany

[3] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230036, Peoples R China

[4] IFW Dresden, Inst Complex Mat, D-01069 Dresden, Germany

[5] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 08期

关键词：

anodes; lithium-ion batteries; nanomembranes; nanotubes; silicon; HIGH-CAPACITY ANODES; RECHARGEABLE BATTERIES; SILICON NANOWIRES; SPACE; FILMS;

D O I：

10.1002/anie.201208357

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rolling their own: Naturally rolled-up C/Si/C trilayer nanomembranes (see scheme) exhibit a high reversible capacity of about 2000 mAh g-1 at 50 mA g-1, and 100 % capacity retention at 500 mA g-1 after 300 cycles. This technique is general and could be applied to the fabrication of other battery materials that undergo large volume changes. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2326 / 2330

页数：5

共 30 条

[1] Building better batteries
Armand, M.
Tarascon, J. -M.
[J]. NATURE, 2008, 451 (7179) : 652 - 657
[2] Amorphous silicon thin films as a high capacity anodes for Li-ion batteries in ionic liquid electrolytes
Baranchugov, V.
Markevich, E.
Pollak, E.
Salitra, G.
Aurbach, D.
[J]. ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (04) : 796 - 800
[3] Bruce P.G., 2008, Angew. Chem, V120, P2972
[4] Nanomaterials for rechargeable lithium batteries
Bruce, Peter G.
Scrosati, Bruno
Tarascon, Jean-Marie
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) : 2930 - 2946
[5] High-performance lithium battery anodes using silicon nanowires
Chan, Candace K.
Peng, Hailin
Liu, Gao
McIlwrath, Kevin
Zhang, Xiao Feng
Huggins, Robert A.
Cui, Yi
[J]. NATURE NANOTECHNOLOGY, 2008, 3 (01) : 31 - 35
[6] Stepwise Nanopore Evolution in One-Dimensional Nanostructures
Choi, Jang Wook
McDonough, James
Jeong, Sangmoo
Yoo, Jee Soo
Chan, Candace K.
Cui, Yi
[J]. NANO LETTERS, 2010, 10 (04) : 1409 - 1413
[7] Silicon Inverse-Opal-Based Macroporous Materials as Negative Electrodes for Lithium Ion Batteries
Esmanski, Alexei
Ozin, Geoffrey A.
[J]. ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (12) : 1999 - 2010
[8] Room-temperature single-phase Li insertion/extraction in nanoscale LixFePO4
Gibot, Pierre
Casas-Cabanas, Montse
Laffont, Lydia
Levasseur, Stephane
Carlach, Philippe
Hamelet, Stephane
Tarascon, Jean-Marie
Masquelier, Christian
[J]. NATURE MATERIALS, 2008, 7 (09) : 741 - 747
[9] Structured silicon anodes for lithium battery applications
Green, M
Fielder, E
Scrosati, B
Wachtler, M
Serra Moreno, J
[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (05) : A75 - A79
[10] Deformations in Si-Li Anodes Upon Electrochemical Alloying in Nano-Confined Space
Hertzberg, Benjamin
Alexeev, Alexander
Yushin, Gleb
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (25) : 8548 - +

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