Chiral dihydroxyacetone equivalents in synthesis: An expedient diastereo- and enantioselective synthesis of differentially protected ketopolyols

被引：0
|
作者：
Enders, D [1 ]
Ince, SJ [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
来源：
SYNTHESIS-STUTTGART | 2002年 / 05期
关键词：
chiral dihydroxyacetone equivalent; alpha-substituted ketones; aldol reactions; polyols; asymmetric synthesis;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A highly diastereo- and enantioselective entry to higher order ketopolyols, employing boron-mediated aldol reactions of a chiral dihydroxyacetone equivalent, is reported. The differentially protected products should prove as useful building blocks for poly-hydroxylated natural product synthesis.
引用
收藏
页码：619 / 624
页数：6
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