Electrophotochemical Decarboxylative Azidation of Aliphatic Carboxylic Acids

被引：52

作者：

Wang, Yukang ^{[1
,2
]}

Li, Liubo ^{[1
]}

Fu, Niankai ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

ACS CATALYSIS | 2022年 / 12卷 / 17期

基金：

中国国家自然科学基金;

关键词：

electrophotocatalysis; decarboxylative functionalization; azidation; dual metal catalysis; flow synthesis; ELECTROCATALYTIC APPROACH; COUPLING REACTIONS; PHOTOREDOX; LIGHT; OXIDATION; ELECTROLYSIS; ALKYLATION; REDUCTION; AMINATION; BEHAVIOR;

D O I：

10.1021/acscatal.2c02934

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report an electrophotochemical metal-catalyzed strategy that harnesses the power of light and electricity for radical decarboxylative functionalization of aliphatic carboxylic acids. This environmentally friendly protocol smoothly converts a diverse array of aliphatic carboxylic acids into the corresponding alkyl azides without using chemical oxidants or azido-group transfer reagents. The visible light energy and electric energy can be applied in a spatially separated fashion with a modular electro-flow-cell for large-scale synthesis.

引用

页码：10661 / 10667

页数：7

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