Vinylcyclopropane Derivatives in Transition-Metal-Catalyzed Cycloadditions for the Synthesis of Carbocyclic Compounds

被引：273
作者：
Jiao, Lei [1 ]
Yu, Zhi-Xiang [1 ]
机构：
[1] Peking Univ, Coll Chem, Beijing 100871, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 78卷 / 14期
基金：
中国国家自然科学基金;
关键词：
INTRAMOLECULAR 5+2 CYCLOADDITIONS; RH(I)-CATALYZED (5+2)+1 CYCLOADDITION; ASYMMETRIC TOTAL-SYNTHESIS; DENSITY-FUNCTIONAL THEORY; NATURAL-PRODUCT SYNTHESIS; DIELS-ALDER REACTION; ENE-VINYLCYCLOPROPANES; VINYL-CYCLOPROPANES; 7-MEMBERED RINGS; ENANTIOSELECTIVE SYNTHESIS;
D O I：
10.1021/jo400609w
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Vinylcyclopropane (VCP) derivatives participate in a variety of transition-metal-catalyzed multicomponent cycloadditions to produce five- to eight-membered carbocycles. Various cycloaddition modes provide novel approaches to mono-, bi-, and polycyclic molecules. In this Synopsis, recent advances in transition-metal-catalyzed VCP cycloadditions are discussed, with a particular emphasis on the influence of VCP substitution pattern on cycloaddition modes. A tabular summary of applications of the VCP cycloadditions in natural product synthesis is also presented.
引用
收藏
页码：6842 / 6848
页数：7
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