Dithiazole-fused naphthalene diimides toward new n-type semiconductors

被引：47

作者：

Chen, Xin ^{[1
]}

Guo, Yunlong ^{[1
]}

Tan, Luxi ^{[1
]}

Yang, Ge ^{[1
]}

Li, Yonghai ^{[1
]}

Zhang, Guanxin ^{[1
]}

Liu, Zitong ^{[1
]}

Xu, Wei ^{[1
]}

Zhang, Deqing ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Organ Solids Lab, Beijing 100190, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2013年 / 1卷 / 06期

关键词：

FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; SINGLE-CRYSTALLINE TRANSISTORS; HIGH-PERFORMANCE; ORGANIC SEMICONDUCTOR; ANISOTROPIC TRANSPORT; CORE; ELECTRON; DESIGN; DERIVATIVES;

D O I：

10.1039/c2tc00308b

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A simple synthetic approach to dithiazole-fused naphthalene diimides 1 and 2 from 2,6-dibromoNDI (2BrNDI) was described. Note that the synthesis did not involve any metallic catalysts. Based on their cyclic voltammograms, the LUMO energies of 1 and 2 were estimated to be -3.99 eV and -3.98 eV, respectively, being lower than that of unsubstituted NDI. Thin films of 1 and 2 show n-type semiconducting behaviors. OFETs of 1 exhibit electron mobility up to 0.15 cm(2) V-1 s(-1) with high on/off ratio (under ambient conditions) after annealing.

引用

页码：1087 / 1092

页数：6

共 50 条

[1] n-Type Organic Semiconductors in Organic Electronics
Anthony, John E.
Facchetti, Antonio
Heeney, Martin
Marder, Seth R.
Zhan, Xiaowei
[J]. ADVANCED MATERIALS, 2010, 22 (34) : 3876 - 3892
[2] Molecular Design and Ordering Effects in π-Functional Materials for Transistor and Solar Cell Applications
Beaujuge, Pierre M.
Frechet, Jean M. J.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (50) : 20009 - 20029
[3] Current Trends in Shrinking the Channel Length of Organic Transistors Down to the Nanoscale
Cao, Yang
Steigerwald, Michael L.
Nuckolls, Colin
Guo, Xuefeng
[J]. ADVANCED MATERIALS, 2010, 22 (01) : 20 - 32
[4] High-Performance Photoresponsive Organic Nanotransistors with Single-Layer Graphenes as Two-Dimensional Electrodes
Cao, Yang
Liu, Song
Shen, Qian
Yan, Kai
Li, Pingjian
Xu, Jun
Yu, Dapeng
Steigerwald, Michael L.
Nuckolls, Colin
Liu, Zhongfan
Guo, Xuefeng
[J]. ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (17) : 2743 - 2748
[5] Naphthalenedicarboximide- vs Perylenedicarboximide-Based Copolymers. Synthesis and Semiconducting Properties in Bottom-Gate N-Channel Organic Transistors
Chen, Zhihua
Zheng, Yan
Yan, He
Facchetti, Antonio
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (01) : 8 - +
[6] General observation of n-type field-effect behaviour in organic semiconductors
Chua, LL
Zaumseil, J
Chang, JF
Ou, ECW
Ho, PKH
Sirringhaus, H
Friend, RH
[J]. NATURE, 2005, 434 (7030) : 194 - 199
[7] Incorporation of fused tetrathiafulvalene units in a DPP-terthiophene copolymer for air stable solution processable organic field effect transistors
Cortizo-Lacalle, Diego
Arumugam, Sasikumar
Elmasly, Saadeldin E. T.
Kanibolotsky, Alexander L.
Findlay, Neil J.
Inigo, Anto Regis
Skabara, Peter J.
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (22) : 11310 - 11315
[8] Dithieno-naphthalimide based copolymers for air-stable field effect transistors: synthesis, characterization and device performance
Dai, Gaole
Chang, Jingjing
Wu, Jishan
Chi, Chunyan
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (39) : 21201 - 21209
[9] Systematic Investigation of Benzodithiophene- and Diketopyrrolopyrrole-Based Low-Bandgap Polymers Designed for Single Junction and Tandem Polymer Solar Cells
Dou, Letian
Gao, Jing
Richard, Eric
You, Jingbi
Chen, Chun-Chao
Cha, Kitty C.
He, Youjun
Li, Gang
Yang, Yang
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (24) : 10071 - 10079
[10] Feng XL, 2009, NAT MATER, V8, P421, DOI [10.1038/NMAT2427, 10.1038/nmat2427]

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