Density-controlled, solution-based growth of ZnO nanorod arrays via layer-by-layer polymer thin films for enhanced field emission

被引:39
作者
Weintraub, Benjamin [1 ]
Chang, Sehoon [2 ]
Singamaneni, Srikanth [2 ]
Han, Won Hee [3 ]
Choi, Young Jin [4 ]
Bae, Joonho [1 ]
Kirkham, Melanie [1 ]
Tsukruk, Vladimir V. [1 ,2 ]
Deng, Yulin [5 ]
机构
[1] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA
[2] Georgia Inst Technol, Sch Polymer Text & Fiber Engn, Atlanta, GA 30332 USA
[3] Myongji Univ, Dept Phys, Yongin 449728, Gyeonggi, South Korea
[4] Myongji Univ, Dept Nano Sci & Engn, Yongin 449728, Gyeonggi, South Korea
[5] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA
关键词
D O I
10.1088/0957-4484/19/43/435302
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A simple, scalable, and cost-effective technique for controlling the growth density of ZnO nanorod arrays based on a layer-by-layer polyelectrolyte polymer film is demonstrated. The ZnO nanorods were synthesized using a low temperature (T = 90 degrees C), solution-based method. The density-control technique utilizes a polymer thin film pre-coated on the substrate to control the mass transport of the reactant to the substrate. The density-controlled arrays were investigated as potential field emission candidates. The field emission results revealed that an emitter density of 7 nanorods mu m(-2) and a tapered nanorod morphology generated a high field enhancement factor of 5884. This novel technique shows promise for applications in flat panel display technology.
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页数:6
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共 30 条
  • [1] Controlled selective growth of ZnO nanorod arrays and their field emission properties
    Ahsanulhaq, Q.
    Kim, Jin-Hwan
    Hahn, Yoon-Bong
    [J]. NANOTECHNOLOGY, 2007, 18 (48)
  • [2] Field emission of individual carbon nanotubes on tungsten tips
    Bai, Xin
    Wang, Mingsheng
    Zhang, Gengmin
    Yu, Jie
    Zhang, Zhaoxiang
    Guo, Dengzhu
    Zhao, Xingyu
    Xue, Zengquan
    [J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2007, 25 (02): : 561 - 565
  • [3] Enhanced field emission of ZnO nanowires
    Banerjee, D
    Jo, SH
    Ren, ZF
    [J]. ADVANCED MATERIALS, 2004, 16 (22) : 2028 - +
  • [4] Bonard JM, 2001, ADV MATER, V13, P184, DOI 10.1002/1521-4095(200102)13:3<184::AID-ADMA184>3.0.CO
  • [5] 2-I
  • [6] BUILDUP OF ULTRATHIN MULTILAYER FILMS BY A SELF-ASSEMBLY PROCESS .3. CONSECUTIVELY ALTERNATING ADSORPTION OF ANIONIC AND CATIONIC POLYELECTROLYTES ON CHARGED SURFACES
    DECHER, G
    HONG, JD
    SCHMITT, J
    [J]. THIN SOLID FILMS, 1992, 210 (1-2) : 831 - 835
  • [7] A CARBON NANOTUBE FIELD-EMISSION ELECTRON SOURCE
    DEHEER, WA
    CHATELAIN, A
    UGARTE, D
    [J]. SCIENCE, 1995, 270 (5239) : 1179 - 1180
  • [8] Inorganic semiconductor nanostructures and their field-emission applications
    Fang, Xiaosheng
    Bando, Yoshio
    Gautam, Ujjal K.
    Ye, Changhui
    Golberg, Dmitri
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (05) : 509 - 522
  • [9] Interface and chain confinement effects on the glass transition temperature of thin polymer films
    Forrest, JA
    DalnokiVeress, K
    Dutcher, JR
    [J]. PHYSICAL REVIEW E, 1997, 56 (05): : 5705 - 5716
  • [10] Microthermal probing of ultrathin polymer films
    Gorbunov, VV
    Fuchigami, N
    Tsukruk, VV
    [J]. HIGH PERFORMANCE POLYMERS, 2000, 12 (04) : 603 - 610