Assessment of the Thermal Processing Behavior of Tobacco Waste

被引:64
作者
Strezov, Vladimir [1 ]
Popovic, Emilija [2 ]
Filkoski, Risto V. [2 ]
Shah, Pushan [1 ]
Evans, Tim [1 ]
机构
[1] Macquarie Univ, Grad Sch Environm, Fac Sci, Sydney, NSW 2109, Australia
[2] Univ Sts Cyril & Methodius, Fac Mech Engn, Skopje, Macedonia
关键词
MALLEE BIOMASS; PYROLYSIS; CONVERSION; BIOSLURRY; MODEL; SLOW; CHAR; OIL;
D O I
10.1021/ef3006004
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Pyrolysis of tobacco waste can provide an effective management option, as it produces biogas and bio-oils, which can be subsequently applied for energy recovery, and biochar, which can be used for carbon sequestration when stored in soils. This work assesses the pyrolysis behavior of tobacco waste and reveals four stage pyrolysis mechanism consisting of dehydration (<200 degrees C), torrefaction (approximate to 300 degrees C), charring (approximate to 500 degrees C), and carbonization (approximate to 750 degrees C). The calorific value of the evolved biogas products at the charring temperature of 500 degrees C was estimated to be reasonably high and the products can be combusted to generate energy required to self-sustain the pyrolysis process. The bio-oils contained complex chemical structure consisting of nicotine, phenols, and organic acids. The biochar product exhibited enrichment in the fixed carbon, ash, and nutrients P and K, while N remained at relatively constant concentration throughout the pyrolysis process.
引用
收藏
页码:5930 / 5935
页数:6
相关论文
共 33 条
[1]  
Briski F, 2003, ACTA CHIM SLOV, V50, P715
[2]  
British American Tobacco, 2011, SUST REP
[3]   Historical developments in hydroprocessing bio-oils [J].
Elliott, Douglas C. .
ENERGY & FUELS, 2007, 21 (03) :1792-1815
[4]  
Encinar JM, 1997, J CHEM TECHNOL BIOT, V70, P400, DOI 10.1002/(SICI)1097-4660(199712)70:4<400::AID-JCTB797>3.0.CO
[5]  
2-6
[6]  
Euromonitor International, 2011, STAT DAT
[7]   Properties of oil and char derived from slow pyrolysis of Tetraselmis chui [J].
Grierson, Scott ;
Strezov, Vladimir ;
Shah, Pushan .
BIORESOURCE TECHNOLOGY, 2011, 102 (17) :8232-8240
[8]   Mathematical model for wood pyrolysis - Comparison of experimental measurements with model predictions [J].
Gronli, MG ;
Melaaen, MC .
ENERGY & FUELS, 2000, 14 (04) :791-800
[9]  
Hanisom A., 2010, ENERG FUEL, V24, P1972
[10]   Measurement of thermal conductivity of cured tobacco material [J].
Kuroiwa, Takayoshi ;
Araki, Norio ;
Nakanishi, Yukio .
FOOD SCIENCE AND TECHNOLOGY RESEARCH, 2008, 14 (02) :124-131