Mild Ullmann-type biaryl ether formation reaction by combination of ortho-substituent and ligand effects

被引：203
作者：
Cai, Q
Zou, BL
Ma, DW
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China
[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 08期
关键词：
biaryl ethers; coupling; ligand effects; ortho effect; peptides;
D O I：
10.1002/anie.200503538
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) An important position: A strong orthosubstituent effect caused by NHCOR groups in 2-haloacetanilides in combination with the ligand effect greatly promotes an Ullmann-type biaryl formation reaction that takes place at room temperature. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：1276 / 1279
页数：4
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