Aerobic Oxidative Dehydrogenation of Amines Catalyzed by a Recoverable Ruthenium Catalyst under Mild Reaction Conditions

被引：24

作者：

Karimi, Babak ^{[1
,2
]}

Yari, Omolbanin ^{[1
]}

Khorasani, Mojtaba ^{[1
]}

Vali, Hojatollah ^{[3
,4
]}

Mansouri, Fariborz ^{[1
]}

机构：

[1] IASBS, Fac Chem, POB 45195-1159, Gava Zang 4513766731, Zanjan, Iran

[2] IASBS, RBST, Res Ctr Basic Sci & Modern Technol, Zanjan 4513766731, Iran

[3] McGill Univ, Dept Anat & Cell Biol, Montreal, PQ H3A 2A7, Canada

[4] McGill Univ, Facil Electron Microscopy Res, Montreal, PQ H3A 2A7, Canada

来源：

CHEMCATCHEM | 2018年 / 10卷 / 08期

基金：

美国国家科学基金会; 加拿大自然科学与工程研究理事会;

关键词：

ionic liquids; mesoporous materials; oxidation; ruthenium; supported catalysts; PERIODIC MESOPOROUS ORGANOSILICA; IONIC-LIQUID FRAMEWORK; EFFICIENT CATALYST; COUPLING REACTION; ALCOHOLS; NITRILES; NANOCATALYST; SELECTIVITY; NANOSPACES; COMPLEX;

D O I：

10.1002/cctc.201701220

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A highly active catalyst based on perruthenate ions supported inside the channels of periodic mesoporous organosilica with a bridged imidazolium ionic liquid framework (Ru@PMO-IL) was developed. The material was found to be an efficient, durable, and recoverable catalyst for the oxidative dehydrogenation of various types of amines such as benzylic, aliphatic, and cyclic aliphatic amines under mild reaction conditions. The products were obtained in excellent yields with excellent selectivities.

引用

页码：1783 / 1787

页数：5

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