Thermal and photochemical ageing of epoxy resin - Influence of curing agents

被引:123
作者
Delor-Jestin, F [1 ]
Drouin, D [1 ]
Cheval, PY [1 ]
Lacoste, J [1 ]
机构
[1] Ecole Natl Chim Clermont Ferrand, Lab Photochim Mol & Macromol, UMR CNRS 6505, F-63177 Clermont Ferrand, France
关键词
epoxy resin; curing agents; ageing; photoacoustic-FTIR; thermal analysis;
D O I
10.1016/j.polymdegradstab.2005.09.009
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The thermal and photochemical ageing of epoxy resin was studied using photoacoustic-FTIR spectroscopy. This technique was satisfactory for both unfilled resin and glass fibre filled epoxy composite. The influence of the curing agent (anhydride or amine) was significant for ageing. The durability of anhydride-epoxy system was the best for both thermal and photoageing. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1247 / 1255
页数:9
相关论文
共 21 条
[1]   PHOTO-OXIDATION OF AMINE CROSSLINKED EPOXIES .2. INFLUENCE OF STRUCTURE [J].
BELLENGER, V ;
VERDU, J .
JOURNAL OF APPLIED POLYMER SCIENCE, 1983, 28 (09) :2677-2688
[2]   Influence of three ageing types (thermal oxidation, radiochemical and hydrolytic ageing) on the structure and gas transport properties of epoxy-amine networks [J].
Damian, C ;
Espuche, E ;
Escoubes, M .
POLYMER DEGRADATION AND STABILITY, 2001, 72 (03) :447-458
[3]   ANALYSIS OF PHOTOOXIDATION OF POLYMER MATERIALS BY PHOTOACOUSTIC FOURIER-TRANSFORM INFRARED-SPECTROSCOPY [J].
DELPRAT, P ;
GARDETTE, JL .
POLYMER, 1993, 34 (05) :933-937
[4]   Thermal analysis of some aromatic amine cured model epoxy resin systems .2. Residues of degradation [J].
Dyakonov, T ;
Mann, PJ ;
Chen, Y ;
Stevenson, WTK .
POLYMER DEGRADATION AND STABILITY, 1996, 54 (01) :67-83
[5]   Testing of organic matrix durability in photochemical ageing using ablation measurements [J].
Guillot, L ;
Monney, L ;
Dubois, C ;
Chambaudet, A .
POLYMER DEGRADATION AND STABILITY, 2001, 72 (02) :209-215
[6]   Effect of structure on thermal behaviour of epoxy resins [J].
Jain, P ;
Choudhary, V ;
Varma, IK .
EUROPEAN POLYMER JOURNAL, 2003, 39 (01) :181-187
[7]   Thermal decomposition kinetics of an epoxy resin with rubber-modified curing agent [J].
Lee, JY ;
Shim, MJ ;
Kim, SW .
JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 81 (02) :479-485
[8]   THERMAL-OXIDATION OF ANHYDRIDE CURED EPOXIES .2. DEPTH DISTRIBUTION OF OXIDATION-PRODUCTS [J].
LEHUY, HM ;
BELLENGER, V ;
PARIS, M ;
VERDU, J .
POLYMER DEGRADATION AND STABILITY, 1992, 35 (02) :171-179
[9]   LOW-TEMPERATURE REARRANGEMENT OF AMINE CURED EPOXY-RESINS [J].
MAXWELL, ID ;
PETHRICK, RA .
POLYMER DEGRADATION AND STABILITY, 1983, 5 (04) :275-301
[10]   Photo-chemical degradation study of an epoxy material by X-ray analysis [J].
Monney, L ;
Rouge, N ;
Dubois, C ;
Chambaudet, A .
POLYMER DEGRADATION AND STABILITY, 1998, 62 (02) :367-371