Novel heptanuclear copper(I) iodide cluster with a pinwheel shape

被引：27
|
作者：
Cheon, Sanghun
Kim, Tae Ho
Jeon, Youngeun
Kim, Jineun [1 ]
Park, Ki-Min
机构：
[1] Gyeongsang Natl Univ, Dept Chem, Jinju 660701, South Korea
来源：
CRYSTENGCOMM | 2013年 / 15卷 / 03期
基金：
新加坡国家研究基金会;
关键词：
LIGANDS; NETWORKS; REARRANGEMENT; POLYMERS; DONOR; CUI;
D O I：
10.1039/c2ce26664d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
From the reaction of CuI with an N,S-donor ligand (L) under different molar ratios, two discrete polynuclear copper(I) iodide complexes, [Cu2I2L2] (1) and [Cu7I7L3] (2) were isolated and characterised. Complex 1 contains a rhomboid-type Cu2I2 cluster, whilst complex 2 is the first example showing a pinwheel-type Cu7I7 cluster.
引用
收藏
页码：451 / 454
页数：4
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