Co-solvent intensification effect on aromatic alcohol oxidation

被引：4

作者：

Chen, Long ^{[1
]}

Chen, Lifang ^{[1
]}

Ye, Yinmei ^{[1
]}

Qi, Zhiwen ^{[1
]}

Freund, Hannsjoerg ^{[2
]}

Sundmacher, Kai ^{[2
,3
]}

机构：

[1] E China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

[2] Max Planck Inst Dynam Complex Tech Syst, D-39106 Magdeburg, Germany

[3] Univ Magdeburg, D-39106 Magdeburg, Germany

来源：

CATALYSIS COMMUNICATIONS | 2012年 / 28卷

基金：

中国国家自然科学基金;

关键词：

Oxidation; Aromatic alcohols; Co-solvent; Ionic liquids; Intensification effect; SELECTIVE OXIDATION; AEROBIC OXIDATION; IONIC LIQUIDS; ALDEHYDES; SOLVENTS; COMPLEX; OXYGEN; TEMPO;

D O I：

10.1016/j.catcom.2012.08.029

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solvent intensification for aromatic alcohol oxidation was performed by experimentally extensive screening. A co-solvent mixture of[Omim]Cl and toluene was found to significantly intensify this class of reactions with high conversion of alcohols (>90%) and high selectivity to their aldehydes (>90%). The intensification effect can be jointly attributed to the interaction of [Omim]Cl with the catalyst WO3 surface, which enhances its catalytic reactivity, and to the aqueous-organic biphasic formation by toluene, which inhibits the over-oxidation of aromatic alcohols. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：143 / 146

页数：4

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