Fabrication of MgO-CaZrO3 refractory composites from Egyptian dolomite as a clinker to rotary cement kiln lining

被引:19
作者
Ewais, Emad M. M. [1 ]
Bayoumi, Ibrahim M. I. [2 ]
机构
[1] Cent Met R&D Inst CMRDI, RCMD, POB 87 Helwan, Cairo 11421, Egypt
[2] Suez Cement, K30 Maadi Ein Sokhna Rd, Cairo 2691, Egypt
关键词
Dolomite; Zirconia; Calcium zirconate; Composite; Properties; Clinker; RCK; BASIC REFRACTORIES; MICROSTRUCTURE;
D O I
10.1016/j.ceramint.2018.02.134
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Dolomite is used as basic lining for rotary cement kiln due its high refractoriness, corrosion resistance against basic environments and high coating performance, but its poor hydration resistance limits its use. In this work, Egyptian dolomite was converted into outstanding refractory magnesia-calcium zirconate composite (M-CZ) by the addition of 37.8-47.8 wt% zirconia. The mixtures were milled, uni-axially formed and fired at a temperature of 1400-1550 degrees C for 2 h. Thermal analysis, phase composition, microstructure, densification parameters, and other technological properties of the fired specimens were investigated. It was found that sintered M-CZ composite with bulk density (3.95 g/cm(3)), cold crushing strength (170 MPa), and high coating ability can be obtained by firing Egyptian dolomite with 37.8 wt% zirconia at temperature 1500 degrees C with the formation of belite as a secondary product. This composite can be nominated to be produced on a large industrial scale.
引用
收藏
页码:9236 / 9246
页数:11
相关论文
共 30 条
[1]  
AZA SD, 1974, BRIT CERAM TRANS J, V73, P109
[2]  
Baudin Carmen, 2010, Advances in Science and Technology, V70, P47, DOI 10.4028/www.scientific.net/AST.70.47
[3]   CaZrO3-MgO structural ceramics obtained by reaction sintering of dolomite-zirconia mixtures [J].
Booth, Fernando ;
Garrido, Liliana ;
Aglietti, Esteban ;
Silva, Abilio ;
Pena, Pilar ;
Baudin, Carmen .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2016, 36 (10) :2611-2626
[4]  
BRAMPTON EC, 1945, J IRON STEEL I, V152, P341
[5]   Improvement in performance of MgO-CaO refractories by addition of nano-sized ZrO2 [J].
Chen, Min ;
Lu, Caiyun ;
Yu, Jingkun .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2007, 27 (16) :4633-4638
[6]   Microstructure and properties of hercynite-magnesia-calcium zirconate refractory mixtures [J].
Contreras, JE ;
Castillo, GA ;
Rodriguez, EA ;
Das, TK ;
Guzmán, AM .
MATERIALS CHARACTERIZATION, 2005, 54 (4-5) :354-359
[7]   CALCULATION OF THE ZRO2-CAO-MGO PHASE-DIAGRAM [J].
DU, Y ;
JIN, ZP ;
HUANG, PY .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1992, 16 (03) :221-230
[8]   NON-ISOTHERMAL, INSITU XRD ANALYSIS OF DOLOMITE DECOMPOSITION [J].
ENGLER, P ;
SANTANA, MW ;
MITTLEMAN, ML ;
BALAZS, D .
THERMOCHIMICA ACTA, 1989, 140 :67-76
[9]   M-CZ composites from Egyptian magnesite as a clinker to RCK refractory lining [J].
Ewais, Emad M. M. ;
Bayoumi, Ibrahim M. I. ;
El-Korashy, Sabry A. .
CERAMICS INTERNATIONAL, 2018, 44 (02) :2274-2282
[10]   Densification and properties of lime withV2O5 additions [J].
Ghosh, A ;
Bhattacharya, TK ;
Maiti, S ;
Mukherjee, B ;
Tripathi, HS ;
Das, SK .
CERAMICS INTERNATIONAL, 2004, 30 (08) :2117-2120