Catalytic enantioselective [4+2]-cycloaddition: a strategy to access aza-hexacycles

被引：286

作者：

Masson, Geraldine ^{[1
]}

Lalli, Claudia ^{[1
]}

Benohoud, Meryem ^{[1
]}

Dagousset, Guillaume ^{[1
]}

机构：

[1] CNRS, Inst Chim Subst Nat, Ctr Rech Gif, F-91198 Gif Sur Yvette, France

来源：

CHEMICAL SOCIETY REVIEWS | 2013年 / 42卷 / 03期

关键词：

DIELS-ALDER REACTIONS; INVERSE-ELECTRON-DEMAND; CHIRAL BRONSTED ACID; ASYMMETRIC-SYNTHESIS; LEWIS-ACID; PHOSPHORIC-ACID; POVAROV REACTION; STEREOCONTROLLED ACCESS; DANISHEFSKYS DIENE; BRASSARDS DIENE;

D O I：

10.1039/c2cs35370a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aza-Diels Alder reaction has become one of the most widely used synthetic tools for the preparation of N-containing 6-membered heterocycles. Numerous important developments have been reported to render this reaction catalytic and enantioselective. This tutorial review highlights strategies and recent advances to achieve high efficiency and selectivity through the use of organocatalysts and transition metal complexes, allowing also the extension of this transformation substrate scope.

引用

页码：902 / 923

页数：22

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