Novel organoantimony compounds [2,6-(OMe)2C6H3]3SbO and [2,6-(OMe)2C6H3]3Sb(NCO)2•0.5(CH3)2CO. Synthesis and structure

被引：7

作者：

Egorova, I. V. ^{[1
]}

Zhidkov, V. V. ^{[1
]}

Grinishak, I. P. ^{[1
]}

Rodionova, N. A. ^{[1
]}

机构：

[1] Blagoveshchensk State Pedag Univ, Ul Lenina 104, Blagoveshchensk 675000, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2016年 / 86卷 / 11期

关键词：

tris(2,6-dimethoxyphenyl)antimony; derivative; X-ray diffraction analysis; TRIPHENYLSTIBINE OXIDE; CRYSTAL-STRUCTURE; PH3SBO/P4S10; SYSTEM; CARBOXYLIC-ACIDS; CARBON-DIOXIDE; ETHYLENE-OXIDE; POLYMERIZATION; TRIPHENYLANTIMONY; DIHYDROXIDE; CONVERSION;

D O I：

10.1134/S1070363216110141

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel organic compounds of antimony(V), tris(2,6-dimethoxyphenyl)antimony diisocyanate and oxide, have been prepared and studied by X-ray diffraction analysis. Antimony atoms in the diisocyanate molecule and in two symmetrically independent molecules of the oxide exhibit trigonal-bipyramidal and tetrahedral coordination, respectively.

引用

页码：2484 / 2491

页数：8

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