CuInS2 sensitized TiO2 hybrid nanofibers for improved photocatalytic CO2 reduction

被引:426
作者
Xu, Feiyan [1 ]
Zhang, Jianjun [1 ]
Zhu, Bicheng [1 ]
Yu, Jiaguo [1 ,2 ]
Xu, Jingsan [3 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Luoshi Rd 122, Wuhan 430070, Hubei, Peoples R China
[2] King Abdulaziz Univ, Fac Sci, Dept Phys, Jeddah 21589, Saudi Arabia
[3] Queensland Univ Technol, Sch Chem Phys & Mech Engn, Brisbane, Qld 4000, Australia
基金
澳大利亚研究理事会;
关键词
TiO2; Nanofiber; CuInS2; nanoplates; Direct Z-scheme heterojunction; Photocatalytic CO2 reduction; NANOTUBE ARRAYS; QUANTUM DOTS; CO2-REDUCTION ACTIVITY; HYDROCARBON FUELS; ANATASE TIO2; PHOTOREDUCTION; NANOCOMPOSITE; CONSTRUCTION; NANOCRYSTALS; FABRICATION;
D O I
10.1016/j.apcatb.2018.02.042
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Photocatalytic CO2 reduction into solar fuels over photocatalysts has theoretically and practically become a hot research topic. Herein, we fabricated a novel hybrid TiO2 nanofiber coated by CuInS2 nanoplates through a hydrothermal method. The materials were characterized by X-ray diffraction, electron microscopes, UV-vis absorption spectra, nitrogen sorption, X-ray photoelectron spectroscopy and electrochemical impudence spectroscopy. The resulting TiO2/CuInS2 hybrid nanofibers exhibit superior photocatalytic activity for CO2 reduction under irradiation, due to the generation of direct Z-scheme heterojunction between TiO2 and CuInS2. This work may provide an alternate methodology to design and fabricate multicomponent TiO2-based photocatalyst for high-efficiency CO2 photoreduction.
引用
收藏
页码:194 / 202
页数:9
相关论文
共 69 条
[21]   Fabrication of n-type CuInS2 modified TiO2 nanotube arrays heterostructure photoelectrode with enhanced photoelectrocatalytic properties [J].
Li, Tingting ;
Li, Xinyong ;
Zhao, Qidong ;
Shi, Yong ;
Teng, Wei .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 156 :362-370
[22]   Enhanced Photocarrier Separation in Hierarchical Graphitic-C3N4-Supported CuInS2 for Noble-Metal-Free Z-Scheme Photocatalytic Water Splitting [J].
Li, Xiaoxue ;
Xie, Keyu ;
Song, Long ;
Zhao, Mengjia ;
Zhang, Zhipan .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (29) :24577-24583
[23]   Octahedral Cu2O-modified TiO2 nanotube arrays for efficient photocatalytic reduction of CO2 [J].
Li, Yanfang ;
Zhang, Wenpei ;
Shen, Xing ;
Peng, Pengfei ;
Xiong, Liangbin ;
Yu, Ying .
CHINESE JOURNAL OF CATALYSIS, 2015, 36 (12) :2229-2236
[24]   A new understanding of the photocatalytic mechanism of the direct Z-scheme g-C3N4/TiO2 heterostructure [J].
Liu, Jianjun ;
Cheng, Bei ;
Yu, Jiaguo .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (45) :31175-31183
[25]   Integrated CO2 capture and photocatalytic conversion by a hybrid adsorbent/photocatalyst material [J].
Liu, Lianjun ;
Zhao, Cunyu ;
Xu, Jinye ;
Li, Ying .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 179 :489-499
[26]   Understanding the Reaction Mechanism of Photocatalytic Reduction of CO2 with H2O on TiO2-Based Photocatalysts: A Review [J].
Liu, Lianjun ;
Li, Ying .
AEROSOL AND AIR QUALITY RESEARCH, 2014, 14 (02) :453-469
[27]   A Review of Direct Z-Scheme Photocatalysts [J].
Low, Jingxiang ;
Jiang, Chuanjia ;
Cheng, Bei ;
Wageh, Swelm ;
Al-Ghamdi, Ahmed A. ;
Yu, Jiaguo .
SMALL METHODS, 2017, 1 (05)
[28]   Heterojunction Photocatalysts [J].
Low, Jingxiang ;
Yu, Jiaguo ;
Jaroniec, Mietek ;
Wageh, Swelm ;
Al-Ghamdi, Ahmed A. .
ADVANCED MATERIALS, 2017, 29 (20)
[29]   Surface modification and enhanced photocatalytic CO2 reduction performance of TiO2: a review [J].
Low, Jingxiang ;
Cheng, Bei ;
Yu, Jiaguo .
APPLIED SURFACE SCIENCE, 2017, 392 :658-686
[30]   Graphene-Based Photocatalysts for CO2 Reduction to Solar Fuel [J].
Low, Jingxiang ;
Yu, Jiaguo ;
Ho, Wingkei .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (21) :4244-4251