Cyclodextrin derivatives that display Enzyme Catalysis

被引：27
作者：
Marinescu, Lavinia [1 ]
Bols, Mikael
机构：
[1] Univ Copenhagen, Dept Chem, DK-2100 Kbh O, Denmark
来源：
TRENDS IN GLYCOSCIENCE AND GLYCOTECHNOLOGY | 2009年 / 21卷 / 122期
关键词：
artificial enzyme; chemzyme; Michaelis-Menten kinetics; rate acceleration; biomimic; ARTIFICIAL REDOX ENZYMES; BETA-CYCLODEXTRIN; ESTER HYDROLYSIS; ACCELERATED CLEAVAGE; RIBONUCLEASE MIMICS; SELECTIVE SYNTHESIS; RATE ENHANCEMENT; PHENYL ACETATES; DIMER CATALYST; METAL CENTERS;
D O I：
10.4052/tigg.21.309
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
So far cyclodextrin have been the most popular and successful scaffold for creation of enzyme mimics and models. In this paper the literature describing cyclodextrin derivatives that perform Michaelis-Menten kinetics is reviewed.
引用
收藏
页码：309 / 323
页数：15
相关论文
共 81 条
[1]   COUPLED CYCLODEXTRIN APPENDING IMIDAZOLE AS AN ENZYME MODEL [J].
AKIIKE, T ;
NAGANO, Y ;
YAMAMOTO, Y ;
NAKAMURA, A ;
IKEDA, H ;
UENO, A ;
TODA, F .
CHEMISTRY LETTERS, 1994, (06) :1089-1092
[2]   SYNTHESIS AND REACTIVITY OF COBALT(III) COMPLEXES BEARING PRIMARY-SIDE AND SECONDARY-SIDE CYCLODEXTRIN BINDING-SITES - A TALE OF 2 CDS [J].
AKKAYA, EU ;
CZARNIK, AW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (25) :8553-8554
[3]   GEOMETRIC EVIDENCE ON THE RIBONUCLEASE MODEL MECHANISM [J].
ANSLYN, E ;
BRESLOW, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (15) :5972-5973
[4]  
Bender M. L., 1984, J INCLUSION PHENOM, V2, P433
[5]   MINIATURE, ORGANIC-MODELS OF CHYMOTRYPSIN BASED ON ALPHA-CYCLODEXTRINS, BETA-CYCLODEXTRINS AND GAMMA-CYCLODEXTRINS [J].
BENDER, ML ;
DSOUZA, VT ;
LU, XL .
TRENDS IN BIOTECHNOLOGY, 1986, 4 (06) :132-135
[6]   Artificial enzymes, "Chemzymes": current state and perspectives [J].
Bjerre, Jeannette ;
Rousseau, Cyril ;
Marinescu, Lavinia ;
Bols, Mikael .
APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2008, 81 (01) :1-11
[7]   Hydrolysis of toxic natural glucosides catalyzed by cyclodextrin dicyanohydrins [J].
Bjerre, Jeannette ;
Nielsen, Erik Holm ;
Bols, Mikael .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (04) :745-752
[8]   Synthesis of some trifluoromethylated cyclodextrin derivatives and analysis of their properties as artificial glycosidases and oxidases [J].
Bjerre, Jeannette ;
Fenger, Thomas Hauch ;
Marinescu, Lavinia G. ;
Bols, Mikael .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2007, 2007 (04) :704-710
[9]   Biomimetic reactions catalyzed by cyclodextrins and their derivatives [J].
Breslow, R ;
Dong, SD .
CHEMICAL REVIEWS, 1998, 98 (05) :1997-2011
[10]   A NOVEL SYNTHESIS OF SUBSTITUTED IMIDAZOLES, AND A REEXAMINATION OF A PURPORTED CHYMOTRYPSIN MODEL [J].
BRESLOW, R ;
CHUNG, S .
TETRAHEDRON LETTERS, 1989, 30 (33) :4353-4356
123456789