Selectivity of the cyclic carbonate formation by fixation of carbon dioxide into epoxides catalyzed by Lewis bases

被引：15
|
作者：
Gomes, Caio Ribeiro [1 ]
Ferreira, Daniele Marcondes [1 ]
Leopoldo Constantino, Carlos J. [1 ]
Perez Gonzalez, Eduardo R. [1 ]
机构：
[1] Unesp Presidente Prudente, Fac Ciencia & Tecnol, Dept Fis Quim & Biol, BR-19060900 Presidente Prudente, SP, Brazil
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 48期
基金：
巴西圣保罗研究基金会;
关键词：
CO2; capture; Cyclic carbonates; Polycarbonate; Selectivity;
D O I：
10.1016/j.tetlet.2008.09.101
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cyclic carbonate and polycarbonate have been selectively obtained with good conversion by coupling carbon dioxide with diglycidylether of bisphenol A. The ruthenium trichloride supported on tetraethylammonium bromide and polyphosphotungstic acid has been found active and selective to produce the corresponding monomeric and polymeric carbonates. These catalysts can be recycled keeping their high product conversion and selectivity. The heteropolyacid itself showed high activity also under supercritical CO2 conditions to yield polycarbonate. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6879 / 6881
页数：3
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