Hydrosilylation of methylhydrosilyl derivatives of 1,1-dimethylhydrazine

被引：1

作者：

Fomina, AN ^{[1
]}

Gostevskii, BA ^{[1
]}

Mirskov, RG ^{[1
]}

Voronkov, MG ^{[1
]}

Rakhtin, VI ^{[1
]}

Lopyrev, VA ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Div, Favorskii Irkutsk Inst Chem, Irkutsk 664003, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 01期

关键词：

Silane; Adduct; Carbon Atom; Dimethyl; Styrene;

D O I：

10.1023/A:1015385010312

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heating of dimethyl (2,2-dimethylhydrazino)si lane and methylbis(2,2-dimethylhydrazino)silane with 1-hexene or styrene in the presence of a catalytic amount of rhodium dicarbonylacetylacetonate gives rise to adducts by the terminal carbon atom (yields 45-84%). The same reactions with phenylacetylene give complex mixtures of products formed primarily by disproportionation of the starting organosilicon reagents.

引用

页码：53 / 54

页数：2

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