Hydrosilylation of methylhydrosilyl derivatives of 1,1-dimethylhydrazine

被引：1
|
作者：
Fomina, AN [1 ]
Gostevskii, BA [1 ]
Mirskov, RG [1 ]
Voronkov, MG [1 ]
Rakhtin, VI [1 ]
Lopyrev, VA [1 ]
机构：
[1] Russian Acad Sci, Siberian Div, Favorskii Irkutsk Inst Chem, Irkutsk 664003, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 01期
关键词：
Silane; Adduct; Carbon Atom; Dimethyl; Styrene;
D O I：
10.1023/A:1015385010312
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Heating of dimethyl (2,2-dimethylhydrazino)si lane and methylbis(2,2-dimethylhydrazino)silane with 1-hexene or styrene in the presence of a catalytic amount of rhodium dicarbonylacetylacetonate gives rise to adducts by the terminal carbon atom (yields 45-84%). The same reactions with phenylacetylene give complex mixtures of products formed primarily by disproportionation of the starting organosilicon reagents.
引用
收藏
页码：53 / 54
页数：2
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