Catalytic Transformations of Molecular Dinitrogen by Iron and Cobalt-Dinitrogen Complexes as Catalysts

被引：14
|
作者：
Kuriyama, Shogo [1 ]
Nishibayashi, Yoshiaki [1 ]
机构：
[1] Univ Tokyo, Sch Engn, Dept Syst Innovat, Bunkyo Ku, Tokyo 1138656, Japan
来源：
NITROGEN FIXATION | 2017年 / 60卷
关键词：
Ammonia; Catalyst; Cobalt; Dinitrogen; Iron; Reduction; Silylamine; COORDINATED DINITROGEN; FE-N-2; COMPLEX; N-2; REDUCTION; NITROGEN; AMMONIA; SILYLATION; MOLYBDENUM; CONVERSION; FIXATION;
D O I：
10.1007/3418_2016_5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This chapter describes the recent advances of the iron and cobalt-catalyzed transformations of molecular dinitrogen into not only silylamine but also ammonia and hydrazine under mild reaction conditions. In both reaction systems, reaction pathways are proposed based on the experimental and theoretical studies on iron and cobalt-dinitrogen complexes.
引用
收藏
页码：215 / 234
页数：20
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