Highly efficient and regioselective couplings of aryl halides to olefins catalyzed by a palladium complex with a hybrid phosphorus-sulfur ligand

被引：53

作者：

Morales-Morales, D

Redón, R

Zheng, YF

Dilworth, JR

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

[2] Univ Hawaii, Dept Chem, Honolulu, HI 96822 USA

[3] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

来源：

INORGANICA CHIMICA ACTA | 2002年 / 328卷 / 01期

关键词：

Heck reaction; P-S hybrid ligands; palladium complexes; catalysis;

D O I：

10.1016/S0020-1693(01)00659-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel palladium phosphino-thioether P-S chelate complex, [PdCl2{MeSC6H4-2-(CH2PPh2)}] (3) is a highly efficient catalyst for the olefinic coupling of aryl bromo and iodo compounds to olefins under aerobic conditions, leading to more than 10(6) turnovers for the reactions with bromo and iodo benzenes. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：39 / 44

页数：6

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